A capillary typically is defined as a tube having a very small inside diameter. Using the previous example as a starting point, a capillary is simply our liquid, solid, gas interface as described above rotated about an offset axis running parallel to the liquid-solid interface. Because of this, the principles involving contact angle and interfacial surface energies still apply.
The primary and most notable difference between the two examples concerns the creation of a contact angle that spans the entire capillary tube. When viewed in a two dimensional fashion, a meniscus is created from the liquid’s contact angle with the solid. As a result and in accordance with the summary of our earlier discussion involving the liquid droplet, we can use the contact angle (or meniscus shape) to determine the relative strengths of the interfacial surface energies.
If the interfacial surface energies are varied, the contact angle (meniscus shape) changes until equilibrium is reestablished. Note the changes that occur in the liquids contact angle (meniscus shape) when the liquid’s surface energy is first increased and then decreased. Then, note the changes that occur to the contact angle (meniscus shape) when the solids surface energy is first increased and then decreased. In both cases, the shape of the contact angle (meniscus shape) conforms to balance interfacial surface energies.